11 - Surface Chemistry Questions Answers

0.25 g lyophilic colloid is added to 100 ml gold solution to prevent the coagulation on adding 1ml 10% NaCl soln . What will be gold number of lyophilic colloid??

Asked By: SARIKA SHARMA
is this question helpfull: 7 0 read solutions ( 1 ) | submit your answer
Joshi sir comment

 “weight of the dried protective agent in milligrams, which when added to 10 ml of a standard gold sol (0.0053 to 0.0058%) is just sufficient to prevent a colour change from red to blue on the addition of 1 ml of 10 % sodium chloride solution, is equal to the gold number of that protective colloid.”

 

0.25 g lyophilic colloid is added to 100 ml gold solution

so 250 mg lyophilic colloid is added to 100 ml gold solution

so 25 mg lyophilic colloid is added to 10 ml gold solution

so answer will be 25

Most effective coagulant for a colloid soln of arsenic sulphide in water is

1) 0.1 M sodium phosphate

2) 0.1M zinc sulphate

3) 0.1 M zinc nitrate

4) 0.1 M aluminium chloride

Plzz annex explanation also

Asked By: SARIKA 19 Day ago
is this question helpfull: 1
Asked By: SARIKA SHARMA
is this question helpfull: 6 0 submit your answer
Joshi sir comment

its 4th option 

because As2Sis usually a negative colloid and positive ion is responsible for its coagulation and according to Hardy Schulze priciple more positive ion will be more effective

which of the following have maximum value of enthalpy of physisorption?

(a) H2

(b) N2

(c) H2O

(d) CH4

Asked By: HIMANSHU MITTAL
is this question helpfull: 8 1 submit your answer
Joshi sir comment

(d) CH4 based on the value of energy which is 6 Kcal/mole for 0.1 milimole/gram and is greatest among the given 4

volume of gases H2 , CH4 , CO2 , and NH3 absorbed by 1g of charcoal at 288K are in the order

Asked By: HIMANSHU MITTAL
is this question helpfull: 3 0 read solutions ( 1 ) | submit your answer
Joshi sir comment

H2        4.7 cc per gm

CH4   16.2 cc per gm

CO   48 cc per gm

NH3   181 cc per gm

there are two radio nuclei A and B. A is α-emitter and B is a β-emitter, their decay constant are in the ratio 1:2. what should be the no. of atoms of A&B at time t=0, so that probability of getting α and β-particles are same at time t=0

(a) 2:1

(b) 1;2

(c) 1:4

(d) 4:1

Asked By: HIMANSHU MITTAL
is this question helpfull: 4 2 submit your answer
Joshi sir comment

its (b)

decay constant ratio = 1:2

so half life ratio = 2:1

so for getting probability of finding alpha and beta same ratio will be 1:2

a carbon sample from the frame of a picture gives 7 counts of C-14 per minute per gram of carbon . if freshly cut wood gives 15.3 counts of C-14 per minute. calculate the age of frame (t½ of C-14 = 5570 yrs)

(a) 6286 yrs

(b) 5527 yrs

(c) 5570 yrs

(d) 4570 yrs

Asked By: HIMANSHU MITTAL
is this question helpfull: 2 0 submit your answer
Joshi sir comment

use t = 2.303/k * log(15.3/7)

k = 0.6932/t1/2

the binding energy per nucleon for C-12 is 7.68 MeV and that for C-13 is 7.47 MeV. calculate the energy required to remove a neutron from C-13

(a) 4.5MeV

(b) 45MeV

(c) 0.45MeV

(d) 0.045MeV

Asked By: HIMANSHU MITTAL
is this question helpfull: 1 0 submit your answer
Joshi sir comment

7.47*13-7.68*12 =  97.11-92.16 = 4.5 Mev approx

1gm of  94Pu-239 is an α-emitter with a half life of 24400 yrs. given 1g sample of this plutonium how many α-particles will it emit per second?

(a) 2.27*10^9

(b) 2.27*10^10

(c) 2.27*10^11

(d) 2.27*10^12

Asked By: HIMANSHU MITTAL
is this question helpfull: 5 1 submit your answer
Joshi sir comment

dn/dt = kn

so dn = (0.6932/24400*3.1*107)*(1/239)*6.023*1023*1

solve 

a radioactive substance (M= 100g/mol) have t½ of 5 days. if today 0.125mg is left over what was its activity 20 days earlier?

(a) 522.8 Ci

(b) 1.93*10^7 Rd

(c) 1.93*10^13 Bq

(d) all of these

Asked By: HIMANSHU MITTAL
is this question helpfull: 2 3 submit your answer
Joshi sir comment

20 day means 4 half lifes so today 0.125mg means 0.125*24 = 2gm earlier 

so activity dn/dt = kn

solve and convert in required units

a uranium mineral contains U-238 and Pb-206 in the ratio 4:1 by weight. Calculate the age of mineral (t½ for U-238 = 4.5 *10^9 years)

(a) 1.45*10^9 yrs

(b) 16.6*10^9 yrs

(c) 16.6*10^10 yrs

Asked By: HIMANSHU MITTAL
is this question helpfull: 2 0 submit your answer
Joshi sir comment

U:Pb = 4:1

taking these ratio as mass

we get the initial mass of U = 4+(1*235/208)

and present mass of U = 4

now use the first order equation of radioactivity

Login Here

Register